Material Safety Data Sheet

Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Nitrile High Performance Plastic Adhesive 1099

MANUFACTURER: 3M

DIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center

St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date:	01/28/2008
Supercedes Date:	09/29/2005
Document Group:	10-2442-1

Product Use:

Specific Use: plastic adhesive

Intended Use: Industrial use

SECTION 2: INGREDIENTS
Ingredient	C.A.S. No.	% by Wt
Acetone	67-64-1	60 - 70
Acrylonitrile-Butadiene Polymer	9003-18-3	10 - 20
Phenolic Resin	25085-50-1	5 - 10
Phenolic Polymer	55185-45-0	5 - 10
Salicylic Acid	69-72-7	1 - 5
Zinc Oxide	1314-13-2	1 - 3

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW

Odor, Color, Grade: White/pink to light tan liquid - ketone odor

General Physical Form: Liquid

Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause target organ effects.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:

Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May be absorbed following inhalation and cause target organ effects.

Ingestion:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature	465 ºC [Details: Acetone]
Flash Point	-4 ºF [Test Method: Closed Cup]
Flammable Limits - LEL	2.6 % volume
Flammable Limits - UEL	12.8 % volume
OSHA Flammability Classification	Class IB Flammable Liquid

5.2 EXTINGUISHING MEDIA

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Contents may be under pressure, open carefully. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Avoid contact with oxidizing agents.

7.2 STORAGE

Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS

Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. If exhaust ventilation is not available, use appropriate respiratory protection.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection

Avoid eye contact with vapors, mists, or spray.

The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.

8.2.2 Skin Protection

Avoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.

Gloves made from the following material(s) are recommended: Butyl Rubber, Polyethylene/Ethylene Vinyl Alcohol.

8.2.3 Respiratory Protection

Avoid breathing of vapors, mists or spray.

Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient	Authority	Type	Limit	Additional Information
Acetone	ACGIH	TWA	500 ppm	Table A4
Acetone	ACGIH	STEL	750 ppm	Table A4
Acetone	OSHA	TWA, Vacated	750 ppm
Acetone	OSHA	TWA	1000 ppm	Table Z-1
Acetone	OSHA	STEL, Vacated	1000 ppm
Zinc Oxide	ACGIH	TWA, respirable	2 mg/m3
Zinc Oxide	ACGIH	STEL	10 mg/m3
Zinc Oxide	OSHA	TWA, as fume	5 mg/m3	Table Z-1
Zinc Oxide	OSHA	TWA, respirable	5 mg/m3	Table Z-1
Zinc Oxide	OSHA	STEL, Vacated, as fume	10 mg/m3
Zinc Oxide Zinc Oxide	OSHA OSHA	TWA, Vacated, as dust TWA, as total dust	10 mg/m3 15 mg/m3	Table Z-1

VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency.

SOURCE OF EXPOSURE LIMIT DATA:

ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline

OSHA: Occupational Safety and Health Administration

AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: White/pink to light tan liquid - ketone odor

General Physical Form: Liquid

Autoignition temperature 465 ºC [Details: Acetone]

Flash Point -4 ºF [Test Method: Closed Cup]

Flammable Limits - LEL 2.6 % volume

Flammable Limits - UEL 12.8 % volume

Boiling point >=56 ºC

Density 0.89 g/ml

Vapor Density 2.0 [Ref Std: AIR=1]

Vapor Pressure <=185 mmHg [@ 68 ºF]

Specific Gravity 0.89 [Ref Std: WATER=1]

pH Not Applicable

Melting point Not Applicable

Solubility in Water Slight (less than 10%)

Evaporation rate 1.9 [Ref Std: ETHER=1]

Hazardous Air Pollutants 0 % weight [Test Method: Calculated]

Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1]

Percent volatile 60 - 70 % weight

VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]

Viscosity 2150 centipoise [@ 73.4 ºF]

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: Strong oxidizing agents; Heat; Sparks and/or flames

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance Condition

Aldehydes During Combustion

Hydrocarbons During Combustion

Carbon monoxide During Combustion

Carbon dioxide During Combustion

Hydrogen Cyanide During Combustion

Ketones During Combustion

Oxides of Nitrogen During Combustion

Oxides of Zinc During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its

components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Reclaim solvent if feasible. Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number	UPC	ID Number	UPC
62-1099-2631-1	00-21200-19808-3	62-1099-2635-2
62-1099-6530-1	00-21200-19811-3	62-1099-7530-0	00-21200-19813-7
62-1099-8530-9	00-21200-19814-4	62-1099-9530-8	00-21200-19815-1
62-1099-9532-4	00-48011-58552-9	62-1099-9535-7	00-21200-30007-3

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient	C.A.S. No	% by Wt
Zinc Oxide (ZINC COMPOUNDS)	1314-13-2	1 - 3

STATE REGULATIONS

Contact 3M for more information.

CHEMICAL INVENTORIES

The components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.

Contact 3M for more information.

INTERNATIONAL REGULATIONS

Contact 3M for more information.

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard Classification

Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Revision Changes:

Section 1: Product name was modified.

Section 1: Product use information was modified. Section 1: Division name was modified.

Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified.

Section 7: Handling information was modified.

Section 8: Engineering controls information was modified. Section 8: Skin protection phrase was modified.

Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 10: Materials and conditions to avoid physical property was modified.

Page Heading: Product name was modified. Section 9: Vapor density value was modified. Section 9: Vapor pressure value was modified. Section 9: Boiling point information was modified.

Section 5: Autoignition temperature information was modified. Section 5: Flash point information was modified.

Sections 3 and 9: Odor, color, grade information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified.

Section 9: pH information was modified.

Section 9: Melting point information was modified. Section 9: Flash point information was modified.

Section 9: Autoignition temperature information was modified. Section 5: OSHA flammability heading was added.

Section 5: OSHA flammability data was added. Section 9: Density information was added.

Section 14: ID Number(s) and/or UPC(s) Template 1 was added. Section 2: Ingredient table was added.

Section 15: EPCRA 313 information was added. Section 15: EPCRA 313 text was added.

Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines legend was added.

Section 8: Exposure guidelines data source legend was added.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF

TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

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